Multifunctional materials
with bioactive effect used in implantology - MULTIBIOMAT
Funding agency: PNCDI II
- CNMP, Project
71-080/2007
Coordinator - “Politehnica” University –
CEMS
Project manager: Prof. Dr. Eng. Georgeta Cosmeleata
Partner - INOE 2000 –Magurele
Partner project manager: Dr. Viorel Braic
Partner - Spital Coltea
Partner project manager:
Dr. Roxana-Nicoleta Siliste
Partner – ZIROM SA
Partner project manager: Eng.
Stefan Crangea
Partner - SC Prelucrari
metalurgice PROD SRL
Partner
project manager: Eng. Dorel
Nedelcu
Objective
Novel coatings
for surface biofunctionalization, design, deposition and tests.
Specific objectives for INOE 2000:
v Novel coatings with bioactive effect for implantology: deposition
and characterization: composition, thickness, adhesion, thickness
Results:
- Deposition
method: reactive magnetron sputtering
Set-up and photograph of the deposition
system
Investigated
coatings: TiNO, ZrNO
Auger
electron spectroscopy spectra of TiNO (left) and ZrNO
(right) coatings
AFM
images of TiNO (left) and ZrNO (right) coatings with
RMS roughness less than 2 nm.
Microhardness of the coatings deposited on different metal
substrates
|
Coating |
Substrate |
HV0.015 (GPa) |
|
TiNO |
316 L |
14 ± 2 |
|
Ti5Al2.5Fe |
12 ±
2 |
|
|
ZrNO |
316 L |
15 ±
3 |
|
Ti5Al2.5Fe |
14 ±
2 |
Adhesion of TiNO (left) and ZrNO (right)
coatings Coatings microhardness
Coatings thickness: 2.2 µm, @ normal force F= 5 N
- Published
papers
-
Preparation and characterization of titanium oxy-nitride thin films, M. Braic, M. Balaceanu, A. Vladescu, A. Kiss,
V. Braic, G. Epurescu, G. Dinescu, A. Moldovan, R. Birjega, M. Dinescu, Applied Surface Science, 253 (2007)
8210-8214, doi: 10.1016/j.apsusc.2007.02.179
-
On some characteristics of Ti oxynitrides obtained by pulsed magnetron sputtering, M. Braic, V. Braic, M. Balaceanu,
A. Kiss, C.M. Cotrut, P. Drob, A. Vladescu,
C. Vasilescu, Plasma Processes and
Polymers, 4 (2007) S171 –S174, doi:
10.1002/ppap.200730605
-
Structural, mechanical
and corrosion properties of TiNO/ZrNO multilayer coatings, M. Balaceanu, V. Braic,
M. Braic, C.N. Zoita, A. Vladescu,
P. Drob, C. Vasilescu, D. Dudu, O. Muresanu, Surface and Coatings
Technology, 202 (2008) 2384-2388, doi: 10.1016/j.surfcoat.2007.09.032
-
Multi-purpose Materials with
Bioactive Effect Intended
for Implantology, I. Nedelcu, G. Cosmeleata,
I. Carceanu, I.A. Cojanu,
D. Nedelcu, M. Braic, Metalurgia International, 14 (2009) 57-60
-
Ti-base alloys functionalized
by biocompatible TiON respectively TiO2 layers, I. Carceanu, A. Veteleanu, I. Nedelcu, P.N. Manicatide,
M. Braic, N. Boca, Metalurgia International, 5 (2011) 38-42
- Presentation
at national and international conferences
1.
Structural, mechanical and
corrosion properties of TiNO/ZrNO multilayer
coatings, A.Vladescu, A.Kiss, V.Braic, C.N.Zoita, P.Drob, M.Balaceanu, C.Vasilescu, M.Braic, Conferinta Internationala E-MRS Spring 2007, Strasbourg, Franta 30
mai-2 iunie 2007.
2.
On some properties of Ti and Zr nitride and
oxynitride multilayer coatings deposited
by the pulsed magnetron sputtering method, M. Braic, M. Balaceanu,
V. Braic, A. Kiss, C. Zoita, A. Vladescu,
MAGNETRON 2008 "5e Journées sur les nouvelles tendances en procédés magnétron et arc pour le
dépôt de couches minces"4 - 5 Juin 2008, Lyon,
France
3.
Preparation and characterization
of Ti and Zr based oxy-nitride thin films, M. Braic, M. Balaceanu,
V. Braic, C.N. Zoita, 8-th International Balkan Workhop on Applied Physics, IBWAP 5-7 Iulie 2008, Constanta
4.
Preparation and biological
evaluation of Zr-based hard coatings for osteosynthesis purposes, M. Balaceanu, A. Vladescu, I. Antoniac, C. Cotrut, M. Braic,
The Eleventh International Conference on Plasma Surface Engineering - PSE 2008-
, 15 – 19 September 2008, Garmisch-Partenkirchen, Germany.
5.
Patents
·
RO128758 (B1)/2018
Thin
bio-active layers for coating orthopedic implants, A. Vladescu,
M. Braic, A. Kiss, V. Braic, M. Balaceanu
·
RO127411 (B1)/2017
Biocompatible
thin films with compositional gradient for covering metal dental implants, A. Vladescu, V. Braic, M. Braic, A. Kiss